Gel
Filled PEI Body PH Electrode With BNC Connector - HI-1230B
The
HI-1230B is a PEI body, double junction pH electrode with a BNC connector.
This electrode has a single ceramic junction in the outer reference cell
and the spherical pH sensing portion is made with high temperature glass
and is protected by an extension of the durable PEI body.
This
design consideration is ideal for field applications as well as general
purpose use.
- Durable
PEI Body
- Double
Junction Reference
- Low
Temperature (LT) Glass
Hanna
Instruments offers a wide variety of pH electrodes that are designed for
many different applications. The type of glass used for sensing pH, bulb
shape, body material, type of junction, type of reference and electrolyte
used are just some of the design considerations.
The
HI1230B uses low temperature (LT) glass, spherical bulb, polyetherimide
(PEI) body, single ceramic frit, and double junction.
Spherical
Bulb
The
spherical bulb is for general purpose use. Other tip shapes include conic
for penetration and flat tip for surface measurements.
PEI
Body
The
body of the HI1230B is composed of polyetherimide (PEI) resin. The PEI
body is suitable for a wide range of applications and excels in field
measurements due to its durability. The shielding around the spherical
glass tip minimizes breakage due to accidental bumping or dropping of the
electrode. The PEI plastic is a high quality plastic that is chemically
resistant to many aggressive chemicals.
Double
Junction Reference
A
double junction electrode has an internal compartment surrounding the
reference wire. Silver ions are present in the electrolyte of the internal
compartment, which houses the Ag/AgCl reference wire; the electrolyte
outside this compartment is silver free. The double junction design means
that virtually no silver from the electrode enters the sample. This design
allows measurement in applications where silver ions in the sample are
undesirable or silver precipitates on the junction are likely to form.
BNC
Connector
The
HI1230B uses a BNC connector. This type of connector is universal in that
it can be used on any pH meter that has the female BNC probe input. Other
type of connectors include DIN, screw type, T-type, and 3.5mm to name a
few. These types of connectors tend to be proprietary for a particular
type of meter and are not interchangeable.
Single
Junction Versus Double Junction PH Electrodes
Conventional
electrodes are normally single junction. As depicted by the figure
above, these electrodes have only a single junction between the internal
reference wire and the external solution. Under adverse conditions, such
as high pressure, high temperature, highly acidic or alkaline solutions,
the positive flow of the electrolyte through the junction is often
reversed resulting in the ingress of sample solution into the reference
compartment. If this is left unchecked, the reference electrode can
become contaminated, leading to complete electrode failure. Another
potential problem with single junction electrodes is the clogging of the
junction due to silver chloride (AgCl) precipitation. Silver can be
easily precipitate in samples that contain Tris buffer or heavy metals.
When the electrolyte solution makes contact with the sample, some AgCl
will precipitate on the external face of the junction. The result is
drifty readings obtained from the sensor.
Hanna’s
double junction system, as the name implies, has two junctions, only one
of which is in contact with the sample as shown in the figure. Under
adverse conditions, the same tendency of sample ingress is evident.
However, as the reference electrode system is separated physically from
the intermediate electrolyte area, the contamination of the electrode is
minimized. The likelihood of clogging of the junction is also reduced
with a double junction electrode since the outer reference cell uses a
fill solution that is “silver-free”. Since there is no silver present,
there is no precipitate that can form to clog the junction.
Measurement
Range |
pH:
0 to 12 |
Reference
Cell Type |
double,
Ag/AgCl |
Junction
Type/Flow Rate |
ceramic,
single / 15-20 µL/h |
Type
of Electrolyte |
gel |
Body
Material |
PEI |
Tip
/ Shape |
spheric
(dia: 7.5 mm) |
Matching
Pin |
no |
Max.
Pressure |
2
bar |
Temperature
Operating Range |
-5
to 70°C (23 to 158°F) – LT |
Body
Length/Overall Length |
120
mm / 163.5 mm |
Temperature
Sensor |
no |
Outer
Diameter |
12
mm |
Cable |
coaxial;
1 m (3.3’) |
Connector
Type |
BNC |
Amplifier |
no |
Recommended
Use |
field
applications |
Brand : Hanna Instruments